Calorimetry of sulfides and sulfide minerals.

synthesis of sulfides from alcohols and thiols in solvent-freeconditions and deoxygenation of sulfoxides

کاتالیست یک سنتز جدید برای تیواترها توصیف شده است. واکنش الکل ها با آریل، هتروآریل و آلکیل تیو ل ها درحضور 1،3،5- تری آزو- 2،4،6- تری فسفرین-2،2،4،4،6،6 هگزاکلراید ((tapc به عنوان یک کاتالیست موُثر، بازده های خوب تا عالی از تیواترها را حاصل می کند. علاوه براین، واکنش تحت شرایط بدون فلز و بدون حلال پیش می رود، بنابراین یک مکمل جالب برای روش های شناخته شده سنتز تیواترها ارائه می دهد. یک مکانیسم ا...

Sulfur Isotope Geochemistry of Sulfide Minerals

Thermodynamic Properties of Uranyl Minerals: Constraints from Calorimetry and Solubility Measurements

More than 50 uranyl minerals, phases containing U as the uranyl UO2 2+ cation, and hydroxide, carbonate, phosphate, and silicate anions, H2O, and alkali and alkaline earth cations, occur in nature and as corrosion products of spent nuclear fuel. Despite their importance and the need to understand their thermodynamics to predict uranium solubility, fate, and transport in the environment, reliabl...

Mineral chemistry of sulfide and sulfosalt minerals in the Cheshmeh-Noghreh barite (gold- silver) deposit, Sabzevar subzone, NE Kashmar

The Sebandoon Barite (gold-silver) deposit is located about 20 km NW of the Kashmar in the Central Iran. The rock units exposed in the area consist of Eocene volcano-sedimentary sequences of lithic tuff, rhyolitic tuff, tuffaceouce shale, lapilli tuff and agglomerate associated with pyroxene andesite and trachyandesite. The barite is composed of lenticular, banded and stockwork mineralization a...

Phase Equilibria in the Metal-Sulfur-Oxygen System Selective Reduction of Metal Oxides and Sulfides: Part I. The Carbothermic Reduction and Calcination of Complex Mineral Sulfides

The difference in the standard Gibbs free energy for the formation of any two oxides or sulfides is the chemical potential for selective reduction of metals from complex minerals. The magnitude of the Gibbs free energy difference is shown by plotting the univariant relationships for relevant sulfides and oxides. In this investigation, three examples of mineral sulfides are considered, and the e...